Hmmm.... there have been former university presidents assume the office of POTUS before: Woodrow Wilson and Dwight Eisenhower.
Which would Daniels more resemble?
Actually, it's amusing that Ike was for a while president of Columbia University between serving as Supreme Commander of the Allied Expeditionary Force in Europe and POTUS. During a search for a new president for Columbia, someone asked who they should consider and was told, "Get Eisenhower", meaning not Ike, but his brother, Milton Eisenhower, who was, at the time president of Kansas State University. He was misunderstood, and Ike got the job.